Preparation of FC(S)SF, FC(S)SeF and FC(Se)SeF through matrix photochemical reactions of F2 with CS2, SCSe, and CSe2

Preparation of FC(S)SF, FC(S)SeF and FC(Se)SeF through matrix photochemical reactions of F2 with CS2, SCSe, and CSe2

The reactions of F-2 with CS2, SCSe, and CSe2, respectively, were analyzed under matrix conditions by co-deposition of the halogen with the triatomic molecules trapped in argon matrices at cryogenic temperatures. In all cases, after co-deposition, the formation of the respective van der Waals comple...

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Veröffentlicht in:Physical chemistry chemical physics : PCCP 2021-10, Vol.23 (37), p.20892-20900
Hauptverfasser: Bava, Yanina B., Cozzarin, Melina, Della Vedova, Carlos O., Willner, Helge, Romano, Rosana M.
Format: Artikel
Sprache:eng
Schlagworte:
Argon
Chemistry
Chemistry, Physical
Codeposition
Cryoforming
Cryogenic temperature
Fluorides
Photochemical reactions
Physical Sciences
Physics
Physics, Atomic, Molecular & Chemical
Science & Technology
Triatomic molecules
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Zusammenfassung:The reactions of F-2 with CS2, SCSe, and CSe2, respectively, were analyzed under matrix conditions by co-deposition of the halogen with the triatomic molecules trapped in argon matrices at cryogenic temperatures. In all cases, after co-deposition, the formation of the respective van der Waals complexes is observed. When each mixture is subsequently irradiated by means of broad-band UV-visible light (200
ISSN:1463-9076
1463-9084
DOI:10.1039/d1cp03764a