Coral Ba/Ca Analysis Using ICP‐OES With an Ultrasonic Nebulizer

The barium/calcium ratio (Ba/Ca) in coral skeletons has been used as a proxy to understand river floods and oceanic upwelling in the tropics and subtropics for the past centuries. Here, we establish a new method for Ba/Ca analysis using inductively coupled plasma optical emission spectrometry (ICP‐O...

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Veröffentlicht in:Geochemistry, geophysics, geosystems : G3 geophysics, geosystems : G3, 2021-08, Vol.22 (8), p.n/a, Article 2021
Hauptverfasser: Watanabe, Takaaki K., Watanabe, Tsuyoshi, Ohmori, Kazuto, Yamazaki, Atsuko
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Sprache:eng
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Zusammenfassung:The barium/calcium ratio (Ba/Ca) in coral skeletons has been used as a proxy to understand river floods and oceanic upwelling in the tropics and subtropics for the past centuries. Here, we establish a new method for Ba/Ca analysis using inductively coupled plasma optical emission spectrometry (ICP‐OES), which has been widely used for coral proxy analyses and can save analysis time compared to other methods. We analyze Ba/Ca by combining an ultrasonic nebulizer with the intensity ratio calibration method to improve the signal intensity of Ba. Our method can determine Ba/Ca in samples with a Ca concentration of 9 mg/L with excellent analytical precision (
ISSN:1525-2027
1525-2027
DOI:10.1029/2021GC009646