Novel multi-stimuli-responsive supramolecular gel based on quinoline for the fluorescence ultrasensitive detection of Fe3+and Cu2

[Display omitted] •Novel supramolecular gel based on quinoline(OMN) with strong AIE effect.•The supramolecular gel shown ultrasensitive sensing ability for Fe3+ and Cu2+.•The test thin film could serve as practical detection application of Fe3+ and Cu2+in aqueous medium. A novel gelator molecular ba...

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Veröffentlicht in:Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy Molecular and biomolecular spectroscopy, 2021-11, Vol.261, p.120078, Article 120078
Hauptverfasser: Wu, Shang, Jiang, Pengwei, Ding, Ning, Hu, Qiang, Yan, Xiangtao, Liu, Jutao, Wang, Yanbin, Zhang, Hong, Yuan, Peilin, Yang, Quanlu
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Sprache:eng
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Zusammenfassung:[Display omitted] •Novel supramolecular gel based on quinoline(OMN) with strong AIE effect.•The supramolecular gel shown ultrasensitive sensing ability for Fe3+ and Cu2+.•The test thin film could serve as practical detection application of Fe3+ and Cu2+in aqueous medium. A novel gelator molecular based on quinolone (MN) has been successfully designed and synthesized. The gelator MN could self-assemble to form a supramolecular gel (OMN), which showed obvious aggregation-induced emission (AIE) in iso-Propyl alcohol (i-PrOH). Furthermore, the supramolecular organogel OMN realized ultrasensitive detection of Fe3+ and Cu2+ in aqueous medium and fluorescent quenching at 427 nm. The sensing mechanism between supramolecular gel and metal ions was fully investigated via FE-SEM, FT-IR, XRD and XPS. Meanwhile, a thin film based on responsive supramolecular gel OMN was prepared, which could be used as multi-stimuli-responsive fluorescent display materials for the detection of Fe3+ and Cu2+.
ISSN:1386-1425
1873-3557
DOI:10.1016/j.saa.2021.120078