An Electrochemical Sensor for H2O2 Based on Au Nanoparticles Embedded in UiO-66 Metal–Organic Framework Films

Precise and real-time detection of hydrogen peroxide (H2O2) is particularly necessary in pharmaceutical, industrial, and military applications because of the strong oxidability of H2O2. Here, an electrocatalytic active film with Au nanoparticles (Au NPs) embedded in a metal–organic framework (UiO-66...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:ACS applied nano materials 2021-06, Vol.4 (6), p.6103-6110
Hauptverfasser: Wang, Qianqian, Zhang, Xuemin, Chai, Xueying, Wang, Tieqiang, Cao, Tianlong, Li, Yunong, Zhang, Liying, Fan, Fuqiang, Fu, Yu, Qi, Wei
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:Precise and real-time detection of hydrogen peroxide (H2O2) is particularly necessary in pharmaceutical, industrial, and military applications because of the strong oxidability of H2O2. Here, an electrocatalytic active film with Au nanoparticles (Au NPs) embedded in a metal–organic framework (UiO-66) film was in situ prepared on the surface of an electrode for H2O2 detection. The size of Au nanoparticles and electrochemical activity of the Au nanoparticles/UiO-66 film could be controlled by manipulating the electrodeposition conditions. Since Au NPs are encapsulated into the pores of the UiO-66 film prepared in situ on a conductive substrate, aggregation of Au nanoparticles could be largely avoided, which promotes the catalytic activity and electron transfer of electrode materials. Therefore, the optimized Au nanoparticles/UiO-66 film sample presented a remarkable electrochemical response toward detection of H2O2 with an extended linear range (0.2–23 mM), a low detection limit (0.045 μM, S/N = 3), high sensitivity (329 μA mM–1 cm–2), and good stability. Furthermore, the as-prepared H2O2 sensor also displayed the advantages of excellent anti-interference performance owing to the size selectivity of the regular triangular opening channel of the UiO-66 film. Combining these advantages, the proposed sensor may open a pathway for high-performance electrochemical sensors and bioelectronics.
ISSN:2574-0970
2574-0970
DOI:10.1021/acsanm.1c00915