Synthesis and optical and electronic properties of one-dimensional sulfoxonium-based hybrid metal halide (CH3)(3)SOPbI3

Synthesis and optical and electronic properties of one-dimensional sulfoxonium-based hybrid metal halide (CH3)(3)SOPbI3

We report the synthesis and optical and electronic properties of a one-dimensional sulfoxonium-based hybrid metal halide in an orthorhombic crystal system with a Pnma space group. To provide direct insights, a method is developed to calculate tolerance factors with the ionic radii of non-spherical c...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2021-06, Vol.57 (47), p.5790-5793
Hauptverfasser: Tanaka, Yuki, Bai, Shiqiang, Wang, Xizu, Tee, Si Yin, Lim, Siew Lay, Ke, Lin, Dolmanan, Surani B., Lee, Coryl Jing Jun, Lim, Poh Chong, Yao, Xiang, Wu, Jishan, Han, Ming-Yong
Format: Artikel
Sprache:eng
Schlagworte:
Chemistry
Chemistry, Multidisciplinary
Physical Sciences
Science & Technology
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Zusammenfassung:We report the synthesis and optical and electronic properties of a one-dimensional sulfoxonium-based hybrid metal halide in an orthorhombic crystal system with a Pnma space group. To provide direct insights, a method is developed to calculate tolerance factors with the ionic radii of non-spherical cations from X-ray crystallographic data.
ISSN:1359-7345
1364-548X
DOI:10.1039/d1cc01386f