Quantifying source contributions for indoor CO2 and gas pollutants based on the highly resolved sensor data

Household air pollution is the dominant contributor to population air pollutant exposure, but it is often of less concern compared with ambient air pollution. One of the major knowledge gaps in this field are detailed quantitative source contributions of indoor pollutants, especially for gaseous compounds. In this study, temporally, spatially, and vertically resolved monitoring for typical indoor gases including CO2, CO, formaldehyde, methane, and the total volatile organic compounds (VOCs) was conducted to address pollution dynamics and major sources in an urban apartment. The indoor concentrations were significantly higher than the simultaneously measured outdoor concentrations. A new statistic approach was proposed to quantitatively estimate contributions of different sources. It was estimated that outdoor CO2 contributed largely to the indoor CO2, while main indoor sources were human metabolism and cooking. Outdoor infiltration and cooking contributed almost equally to the indoor CO. The contribution of outdoor infiltration to methane was much higher than that to formaldehyde. Cooking contributed to 24%, 19%, and 25% of indoor formaldehyde, methane, and VOCs, whereas the other unresolved indoor sources contributed 61%, 19%, and 35% of these pollutants, respectively. Vertical measurements showed that the uplifting of hot air masses led to relatively high concentrations of the pollutants in the upper layer of the kitchen and in the other rooms to a lesser extent. [Display omitted] •It is important to capture spatial, vertical and temporal variations of indoor gases.•A new statistical approach was developed to quantify source contributions based on highly resolved temporal information.•Outdoor infiltration and cooking contributed almost equally to the indoor carbon monoxide.•Contribution of outdoor infiltration to methane was much higher than that to formaldehyde.•Uplifting of hot air masses led to vertical variations of indoor air pollution.