Controllable design of defect-rich hybrid iron oxide nanostructures on mesoporous carbon-based scaffold for pseudocapacitive applications

The controllable design of functional nanostructures for energy and environmental applications represents a critical yet challenging technology. The existing fabrication strategies focus mainly on increasing the number of accessible active sites. However, these techniques generally necessitate complex chemical agents and suffer from limited experimental conditions delivering high costs, low yields, and poor reproducibility. The present work reports a new strategy for controllable synthesis of a hybrid system including mixed iron oxide nanostructures enriched with non-stoichiometric Fe 21.34 O 32 and Fe 3+ [Fe 5/3 3+ 1/3 2+ ]O 4 phases, which possess a high concentration of oxygen and Fe 2+ vacancies, and a mesoporous carbon-based scaffold (MCS), which was dervied from coffee residues, with graphitic surface and perforated architecture. The nanoperforates acted as trapping sites to localise the Fe x O y nanoparticles, thereby boosting the density of accessible active sites. Additionally, at the interfacial regions between the Fe x O y crystallites, a high density of oxygen vacancies with an oriented pattern was shown to create superlattice structures. The energy storage functionality of the defect-rich MCS/Fe x O y nanostructure with nanoperforated architecture was investigated, where the results exhibited a high gravimetric capacitance of 540 F g −1 at a current density of 1 A g −1 with outstanding capacitance retention of 73.6% after 14 000 cycles. This work reports fabrication of defect-rich iron oxides and carbon-based scaffolds, with perforated architecture. The nanoperforates act as trapping sites to localise the Fe x O y and enhance accessibility of the active sites, improving the electrochemical performance.