Morphology, Dielectric and EMI Shielding Characteristics of Graphene Nanoplatelets, Montmorillonite Nanoclay and Titanium Dioxide Nanoparticles Reinforced Polyvinylidenefluoride Nanocomposites

Herein, flexible polyvinylidenefluoride (PVDF) nanocomposite films reinforced with different concentrations of graphene nanoplatelets (GNPs), montmorillonite (MMT) nanoclay and titanium dioxide (TiO 2 ) nanoparticles (NPs) were prepared using a simple and low-cost solution casting method. The surface morphology of PVDF/GNPs/TiO 2 /MMT nanocomposites and the interaction between PVDF, GNPs, TiO 2 NPs and MMT nanofillers was examined using Fourier transform infrared (FTIR) spectroscopy, X-ray diffraction (XRD) and field emission scanning electron microscopy (FESEM) techniques. The dielectric properties of the prepared nanocomposite films were evaluated using a frequency response impedance analyzer in the frequency range from 50 Hz to 20 MHz at various temperatures. The electromagnetic interference (EMI) shielding effectiveness (SE) of PVDF/GNPs/TiO 2 /MMT nanocomposites was measured in the Ku-band region (12–18 GHz) and the maximum SE of 12.6 dB was obtained for nanocomposites with GNPs-2.5%, MMT-1% and TiO 2 -11.5%. Considering the excellent EMI shielding performance, these nanocomposites can have promising applications in smart electronics and flexible devices.