A Sensitive SiO2@Fe3O4/GO Nanocomposite Modified Ionic Liquid Carbon Paste Electrode for the Determination of Cabergoline

In this study, the initial report on determining cabergoline via nanostructure-adjusted ionic liquid carbon paste electrode with aqueous solutions is described. For this purpose, an original adjusted carbon paste electrode that uses SiO2@Fe3O4/GO nanocomposite and 1-methyl-3-butylimidazolium bromide...

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Veröffentlicht in:Iranian journal of chemistry & chemical engineering 2020-08, Vol.39 (4), p.11-22
Hauptverfasser: Baniasadi, Mohammad, Maaref, Hamed, Dorzadeh, Athareh, Mohammad Alizadeh, Parsa
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Sprache:eng
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Zusammenfassung:In this study, the initial report on determining cabergoline via nanostructure-adjusted ionic liquid carbon paste electrode with aqueous solutions is described. For this purpose, an original adjusted carbon paste electrode that uses SiO2@Fe3O4/GO nanocomposite and 1-methyl-3-butylimidazolium bromide as a binder (SiO2@Fe3O4/GO/CPILE) was designed. Cabergoline oxidation peak at SiO2@Fe3O4/GO/CPILE surface was 500 mV that was approximately 200 mV less compared to the oxidation potential pertaining to the CPE surface subjected to a similar state. Moreover, there was an increase in the peak current of approximately 3.0 times greater at SiO2@Fe3O4/GO/CPILE surface in comparison to that of the CPE. The relevant linear response range and detection limit were determined as 0.07-500.0 and 0.01 mu M, correspondingly. The adjusted electrode was successful in determining cabergoline within real specimens entailing adequate results.
ISSN:1021-9986
1021-9986
DOI:10.30492/IJCCE.2020.105268.3508