Fabrication of ILs-Assisted AgTaO(3)Nanoparticles for the Water Splitting Reaction: The Effect of ILs on Morphology and Photoactivity

The design of an active, stable and efficient photocatalyst that is able to be used for hydrogen production is of great interest nowadays. Therefore, four methods of AgTaO(3)perovskite synthesis, such as hydrothermal, solvothermal, sol-gel and solid state reactions, were proposed in this study to identify the one with the highest hydrogen generation efficiency by the water splitting reaction. The comprehensive results clearly show that the solid state reaction (SSR) led to the obtainment of a sample with an almost seven times higher photocatalytic activity than the other methods. Furthermore, four ionic liquids, all possessing nitrogen in the form of organic cations (two imidazoliums with different anions, ammonium and tetrazolium), were used for the first time to prepare composites consisting of AgTaO(3)modified with IL and Pt, simultaneously. The effect of the ionic liquids (ILs) and Pt nanoparticles' presence on the structure, morphology, optical properties, elemental composition and the effectiveness of the hydrogen generation was investigated and discussed. The morphology investigation revealed that the AgTaO(3)photocatalysts with the application of [OMIM]-cation based ILs created smaller granules (