Photoredox-catalyzed dicarbofunctionalization of styrenes with amines and CO2: a convenient access to γ-amino acids

A visible-light-promoted carbocarboxylation of styrenes using CO(2)and amines is reported. The reaction is catalyzed by a photoredox catalyst and is compatible with a variety of amines and styrenes. This method affords highly functionalized gamma-amino acids in good yields with high regioselectivity...

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Veröffentlicht in:	Green chemistry : an international journal and green chemistry resource : GC 2020-09, Vol.22 (18), p.5961-5965
Hauptverfasser:	Zhang, Bo, Yi, Yaping, Wu, Zhong-Qian, Chen, Chao, Xi, Chanjuan
Format:	Artikel
Sprache:	eng
Schlagworte:	Amines Amino acids Carbon dioxide Catalysts Chemistry Chemistry, Multidisciplinary Green & Sustainable Science & Technology Green chemistry Photoredox catalysis Physical Sciences Regioselectivity Science & Technology Science & Technology - Other Topics Styrenes
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Beschreibung
Zusammenfassung:	A visible-light-promoted carbocarboxylation of styrenes using CO(2)and amines is reported. The reaction is catalyzed by a photoredox catalyst and is compatible with a variety of amines and styrenes. This method affords highly functionalized gamma-amino acids in good yields with high regioselectivity.
ISSN:	1463-9262 1463-9270
DOI:	10.1039/d0gc02254c