Rapid metal-free synthesis of pyridyl-functionalized conjugated microporous polymers for visible-light-driven water splitting

Rapid metal-free synthesis of pyridyl-functionalized conjugated microporous polymers for visible-light-driven water splitting

A rapid metal-free synthetic approach was applied to synthesize pyridyl-functionalized conjugated microporous polymers (PCMPs) via an aminative cyclization between aryl aldehydes and ketones without any metal catalysts. PCMPs exhibited suitable electronic structures for visible-light-driven water sp...

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Veröffentlicht in:Polymer chemistry 2020-05, Vol.11 (2), p.3393-3397
Hauptverfasser: Cheng, Zhonghua, Wang, Lei, He, Yan, Chen, Xingjia, Wu, Xiaojun, Xu, Hangxun, Liao, Yaozu, Zhu, Meifang
Format: Artikel
Sprache:eng
Schlagworte:
Aldehydes
Aromatic compounds
Chemical synthesis
Ketones
Photoelectric effect
Photoelectric emission
Physical Sciences
Polymer chemistry
Polymer Science
Polymers
Science & Technology
Water splitting
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Zusammenfassung:A rapid metal-free synthetic approach was applied to synthesize pyridyl-functionalized conjugated microporous polymers (PCMPs) via an aminative cyclization between aryl aldehydes and ketones without any metal catalysts. PCMPs exhibited suitable electronic structures for visible-light-driven water splitting, offering numerous opportunities in developing new polymer photocatalysts for future solar-to-chemical conversion. A rapid metal-free synthetic approach was applied to synthesize pyridyl-functionalized conjugated microporous polymers (PCMPs) via an aminative cyclization between aryl aldehydes and ketones without any metal catalysts.
ISSN:1759-9954
1759-9962
DOI:10.1039/d0py00249f