Highly efficient removal of Cr(III)-poly(acrylic acid) complex by coprecipitation with polyvalent metal ions: Performance, mechanism, and validation

The Cr(III)-organic complexes formed between Cr(III) and multifunctional group ligands, such as polyacrylate, are highly water soluble and difficult to be removed from wastewater by common treatments. A novel strategy for efficiently removing Cr(III)-poly (acrylic acid) complex (Cr(III)-PAA) from wastewater without introducing secondary pollution is proposed using a coprecipitation method with polyvalent metal ions. Al(III), Fe(III), Zr(IV), and Ti(IV) were combined with the carboxyl of Cr(III)-PAA to decrease hydrophilia and achieve fast and efficient coprecipitation. Cr(III)-PAA was efficiently removed from wastewater by using these polyvalent metal ions, especially at low pH, where the ions exist as monomer. The residual concentration of Cr(III) in treated wastewater under the optimized experimental condition was less than 1.0 mg/L. No Cr(VI) and negligible amount of polyvalent metal ions were detected in the treated wastewater, indicating that almost all of the ions coprecipitated with Cr(III)-PAA. No secondary pollution also occurred. The high reactivity between the polyvalent metal ions and Cr(III)-PAA and the sharp decrease in the hydrophilia of the complex contributed to its highly efficient removal from wastewater. Actual tannery wastewater containing Cr(III)-organic complexes with high solubility and stability was treated through coprecipitation with Al(III). A high Cr(III) removal efficiency of 99.0% was obtained. This work provides new insights into the removal of soluble Cr(III)-organic complexes from wastewater by using an environment-friendly and cost-effective method. [Display omitted] •Coprecipitation was first used to remove Cr(III)-organic complexes from wastewater.•Highly efficient removal of Cr(III)-organic complexes was obtained.•No Cr(VI) and negligible polyvalent metal ions were detected in wastewater.•Blocking the hydrophilic groups of Cr(III)-organic complexes led to rapid removal.•This work provides new insights into the treatment of Cr(III)-organic complexes.