Facile assembly of three cycloalkyne-modules onto a platform compound bearing thiophene S,S-dioxide moiety and two azido groups

Facile assembly of three cycloalkyne-modules onto a platform compound bearing thiophene S,S-dioxide moiety and two azido groups

An efficient method to assemble three cycloalkyne-modules onto a platform compound bearing a thiophene S,S-dioxide moiety and two azido groups has been developed. The sequential reactions without catalysis or additives enabled the facile preparation of trifunctional molecules by a simple procedure....

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2020-04, Vol.56 (34), p.4720-4723
Hauptverfasser: Meguro, Tomohiro, Sakata, Yuki, Morita, Takamoto, Hosoya, Takamitsu, Yoshida, Suguru
Format: Artikel
Sprache:eng
Schlagworte:
Additives
Assembly
Chemistry
Chemistry, Multidisciplinary
Dioxides
Modules
NMR
Nuclear magnetic resonance
Physical Sciences
Science & Technology
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Beschreibung
Zusammenfassung:An efficient method to assemble three cycloalkyne-modules onto a platform compound bearing a thiophene S,S-dioxide moiety and two azido groups has been developed. The sequential reactions without catalysis or additives enabled the facile preparation of trifunctional molecules by a simple procedure. One-pot assembly was also achieved using the platform and three cycloalkynes.
ISSN:1359-7345
1364-548X
DOI:10.1039/d0cc01810d