Crystallization characteristics of Ni-W-P composite coatings reinforced by CeO2 and SiO2 nano-particles

Ni-W-P composite coatings reinforced by CeO 2 and SiO 2 nano-particles on the surface of common carbon steels, were prepared by double pulse electrodeposition. The crystallization course was characterized by phase structures, crystallinity, grain sizes and microstructures. The results indicate that as-deposited composite coating is amorphous. Whereas it turns into the crystalline structure with 98.25% crystallinity, and Ni 3 P, Ni 2 P and Ni 5 P 2 alloy phases precipitate from structures at 400 °C. Thereafter, Ni 2 P and Ni 5 P 2 metastable alloy phases turn into Ni 3 P stable alloy phase at 500 °C. The crystallization course of the composite coating has finished when being heat-treated at 700 °C. The average sizes of Ni grains increase with the rise of heat treatment temperature from 400 °C to 700 °C. CeO 2 and SiO 2 nano-particles deposited into Ni-W-P alloys can delay the crystallization course and habit the growth of alloy phases.