Preparation and characterization of flower-like SrAl2O4:Eu2+,Dy3+ phosphors by sol-gel process

O6; A flower-like Eu2+ and Dy3+ co-doped SrAl2O4 long-lasting phosphorescent (LLP) phosphor was synthesized via the inorganicsalt-based sol-gel method. The crystal structure, morphology and optical properties of the composite were characterized.X-ray diffraction diffusion (XRD) data and DSC-TG curve...

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Veröffentlicht in:Journal of rare earths 2011-01, Vol.29 (1), p.39-43
Hauptverfasser: XIAO, Liyuan, XIAO, Qin, LIU, Yingliang
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Sprache:eng
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Zusammenfassung:O6; A flower-like Eu2+ and Dy3+ co-doped SrAl2O4 long-lasting phosphorescent (LLP) phosphor was synthesized via the inorganicsalt-based sol-gel method. The crystal structure, morphology and optical properties of the composite were characterized.X-ray diffraction diffusion (XRD) data and DSC-TG curves of the phosphor revealed that the SrAl2O4 crystallites have been formed after the precursor was calcined at 900℃ and to be single-phase SrAl2O4 at 1100℃. The SEM photographs indicated that the sample exhibited a universal flower-like morphology with crystallite size of about 1-2μm. After being irradiated with ultraviolet (UV) light, the flower-like phosphor emitted long-lasting green phosphorescence with an excitation peak at 365 nm and emission peak at 500 nm which was ascribed to the characteristic 5d-4f transition of Eu2+.Both the PL spectra and the luminance decay curve revealed that this phosphor exhibited efficient luminescence and long lasting properties.
ISSN:1002-0721
DOI:10.1016/S1002-0721(10)60405-X