Ordered macroporous structured TiO2-based photocatalysts for CO2 reduction: A review

Herein, we review the significant of ordered macroporous (OM) TiO2-based catalysts for boosting photocatalytic CO2 reduction. Based on the need to improve the three key factors of photogenerated charge separation efficiency, solar energy utilization and CO2 adsorption rate during the conversion of CO2 to H2O, we summarized five modification measures: including doping ions into OM TiO2, introducing second semiconductor coupling and noble metal nanoparticles for fabricating multiple Z-scheme heterojunctions, constructing hierarchical pore and carbon-loaded OM TiO2 materials, which effectively enhance the absorption rate of visible light, the separation rate of electrons-hole pairs and the selection of multiple active sites. The OM structured TiO2-based photocatalysts solve the single or multiple key factors for enhancing photocatalytic performances during CO2 conversion. The catalytic mechanism and pathways of OM structured TiO2-based photocatalysts for CO2 reduction are discussed and summarized. It provides new insights on the development of high-efficient catalyst for photocatalytic CO2 conversion to solar fuels. Typical surface modification of TiO2 for enhanced photocatalytic CO2 reduction is reviewed in detail. [Display omitted]