Efficient degradation of sulfacetamide by CoFe PBAs and PBA@PVDF composite membrane activating peroxymonosulfate

More and more antibiotics that are difficult to biodegrade have been detected in water environments threatening ecosystems and human health.Therefore,it is urgent to develop efficient water treatment methods to degrade antibiotics.In this work,Co-Fe Prussian blue analogues(PBAs)with different mo-lar ratios were synthesized for peroxymonosulfate(PMS)activation to degrade sulfacetamide(SAM,10 mg/L).By increasing Co molar ratio,the PMS activation capability and electrochemical properties of PBAs were enhanced.Due to its excellent reactivity(degradation efficiency of 84.2％and mineralization efficiency of 52.79％),cost benefit(electrical energy per order,0.01019 kWh/L)and lower metal leaching([Co]=0.259 mg/L,[Fe]=0.128 mg/L),PBA-1,the as-prepared catalyst with a molar ratio of cobalt to iron of 1∶1,was selected for further study.The radical scavenging experiments and an electron paramagnetic resonance(EPR)trapping experiments were performed and revealed that PBA-1 addition was required to produced·OH and SO4·-from PMS activation.Accordingly,we proposed a PMS activation mechanism and SAM decomposition pathways for PBA-1/PMS reaction system.Besides,a PBA-1@polyvinylidene fluoride(PVDF)catalytic membrane was further prepared to expand the application potential of PBA nanoparti-cles.The PBA-1@PVDF catalytic membrane was highly effective and exhibited a great reusability;thus,it could be considered for applications in actual water treatment processes.