Aggregation-induced emission enhancement of yellow photoluminescent carbon dots for highly selective detection of environmental and intracellular copper(II) ions

Photoluminescent (PL) carbon nanodots (CDs) are prepared through a simple one-step hydrothermal treatment ofo-phenylendiamine (OPD), and the as-prepared OPD-CDs show yellow PL emission under the ultraviolet excitation, which can be further enhanced by Cu2+ions owing to Cu2+ions induced aggregation of OPD-CDs through the coordination of Cu2+ with amino groups on the surface of OPD-CDs. [Display omitted] Carbon dots (CDs) are prepared through a simple one-step hydrothermal treatment of o-phenylendiamine (OPD) and show yellow photoluminescent (PL) emission under the ultraviolet excitation, which can be further enhanced by Cu2+ ions owing to Cu2+ ions induced aggregation of OPD-CDs through the coordination of Cu2+ with amino groups on the surface of OPD-CDs. The aggregation induced emission enhancement (AIEE) property enables it feasible to develop a simple, sensitive and selective method to detect environmental and intracellular copper (II) ions. The limit of detection as low as 0.28μmol/L (3σ/k) and a dynamic range from 0.5 μmol/L to 40μmol/L make it very easy to detect the copper content in water samples, such as river closure reservoir. Furthermore, fluorescence imaging of intracellular Cu2+ suggests that the AIEE features of OPD-CDs specific to Cu2+ ions can be also applied in biological systems.