A new family of supramolecular multiferrocenyl rhomboids：Synthesis,characterization,and their electrochemical behavior

A new family of supramolecular multiferrocenyl rhomboids：Synthesis,characterization,and their electrochemical behavior

Two novel,supramolecular,multiferrocenyl rhomboids 5 and 6 have been successfully constructed from newly designed 60 ferrocenyl donor precursor 1 via coordination-driven self-assembly.The structures of all multiferrocenyl rhomboids were characterized by multinuclear NMR（~1H and ~（31）P）,CSI-TOF-MS, a...

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Veröffentlicht in:Chinese chemical letters 2013-06, Vol.24 (6), p.471-474
Hauptverfasser: Ou-Yang, Jiang-Kun, Chen, Li-Jun, Xu, Lin, Wang, Cui-Hong, Yang, Hai-Bo
Format: Artikel
Sprache:eng
Schlagworte:
Coordination-driven self-assembly
Electrochemical behavior
Multiferrocenyl rhomboid
Supromolecular metallacycle
二茂铁基
合成
家庭
核磁共振
电化学行为
菱形
表征
超分子
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Beschreibung
Zusammenfassung:Two novel,supramolecular,multiferrocenyl rhomboids 5 and 6 have been successfully constructed from newly designed 60 ferrocenyl donor precursor 1 via coordination-driven self-assembly.The structures of all multiferrocenyl rhomboids were characterized by multinuclear NMR（~1H and ~（31）P）,CSI-TOF-MS, and PM6 semi-empirical molecular simulation,and their electrochemical behaviors have been investigated.
ISSN:1001-8417
1878-5964
DOI:10.1016/j.cclet.2013.03.055