Efficient synthesis of the C/D rings of atisine-type C20-diterpenoid alkaloids

A bicyclo[2.2.2]octane C/D ring system, with a lactonic ring at C-8 and C-9, of the atisine-type C20-diterpenoid alkaloids, was successfully synthesized, using an oxidative dearomatization/intramolecular Diels-Alder reaction.

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Bibliographische Detailangaben
Veröffentlicht in:	Chinese chemical letters 2012-12, Vol.23 (12), p.1378-1380
Hauptverfasser:	Chen, De Lin, Wang, Feng Peng
Format:	Artikel
Sprache:	eng
Schlagworte:	C20-diterpenoid alkaloids Diels-Alder反应 ne型 Oxidative dearomatization/intramolecular Diels–Alder reaction 二萜生物碱分子内氧化性芳构化反应高效合成
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Beschreibung
Zusammenfassung:	A bicyclo[2.2.2]octane C/D ring system, with a lactonic ring at C-8 and C-9, of the atisine-type C20-diterpenoid alkaloids, was successfully synthesized, using an oxidative dearomatization/intramolecular Diels-Alder reaction.
ISSN:	1001-8417 1878-5964
DOI:	10.1016/j.cclet.2012.11.004