A novel chemosensor-bipyridyl end capped hyperbranched conjugated polymer
A novel hyperbranched conjugated chemosensor with bipyridyl groups as periphery groups(BPY-HPV) was synthesized.BPY-HPV was highly sensitive to metal ions(Cu~(2+),Ni~(2+)) for the strong coordination interaction(K_(sv) at the order of 10~7 mol~(-1) L) monitored by fluorescence spectroscopy.Moreover,...
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Veröffentlicht in: | Chinese chemical letters 2011-06, Vol.22 (6), p.725-728 |
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Hauptverfasser: | , , , |
Format: | Artikel |
Sprache: | eng |
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Zusammenfassung: | A novel hyperbranched conjugated chemosensor with bipyridyl groups as periphery groups(BPY-HPV) was synthesized.BPY-HPV was highly sensitive to metal ions(Cu~(2+),Ni~(2+)) for the strong coordination interaction(K_(sv) at the order of 10~7 mol~(-1) L) monitored by fluorescence spectroscopy.Moreover,by hydrogen bonds and charge transfer interaction,BPY-HPV shows strong interaction with 1,1,2,2-tetrachloroethane whatever in CH_2Cl_2(K_(sv)~10~6 mol~(-1) L) or film. |
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ISSN: | 1001-8417 1878-5964 |
DOI: | 10.1016/j.cclet.2010.12.024 |