A novel chemosensor-bipyridyl end capped hyperbranched conjugated polymer

A novel hyperbranched conjugated chemosensor with bipyridyl groups as periphery groups(BPY-HPV) was synthesized.BPY-HPV was highly sensitive to metal ions(Cu~(2+),Ni~(2+)) for the strong coordination interaction(K_(sv) at the order of 10~7 mol~(-1) L) monitored by fluorescence spectroscopy.Moreover,...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Chinese chemical letters 2011-06, Vol.22 (6), p.725-728
Hauptverfasser: Meng, Xin, He, Qing Guo, Cao, Hui Min, Cheng, Jian Gong
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:A novel hyperbranched conjugated chemosensor with bipyridyl groups as periphery groups(BPY-HPV) was synthesized.BPY-HPV was highly sensitive to metal ions(Cu~(2+),Ni~(2+)) for the strong coordination interaction(K_(sv) at the order of 10~7 mol~(-1) L) monitored by fluorescence spectroscopy.Moreover,by hydrogen bonds and charge transfer interaction,BPY-HPV shows strong interaction with 1,1,2,2-tetrachloroethane whatever in CH_2Cl_2(K_(sv)~10~6 mol~(-1) L) or film.
ISSN:1001-8417
1878-5964
DOI:10.1016/j.cclet.2010.12.024