Stereoselective Addition of N-Alkylhydroxylamines to α,β-Unsaturated Nitro Compounds

Stereoselective Addition of N-Alkylhydroxylamines to α,β-Unsaturated Nitro Compounds

O6; N-Alkylhydroxylamines have been shown to undergo a stereospecific cis addition to 1-phenyl-2 -nitropropene compounds, whereas the corresponding O-alkylhydroxylamines give no diastereoselectivity. The concerted addition mechanism was provided to explain the difference.

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:中国化学快报（英文版） 2006-07, Vol.17 (7), p.859-862
Hauptverfasser: Ai Jun LI, Ji Cheng CHU, Hong Sheng GUO, Xue Qin ZHOU, Dong Zhi LIU
Format: Artikel
Sprache:eng
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:O6; N-Alkylhydroxylamines have been shown to undergo a stereospecific cis addition to 1-phenyl-2 -nitropropene compounds, whereas the corresponding O-alkylhydroxylamines give no diastereoselectivity. The concerted addition mechanism was provided to explain the difference.
ISSN:1001-8417