Recognition Interactions of Metal-complexing Imprinted Polymer

O6; Molecularly imprinted polymer, exhibiting considerable enantioselectivity for L-mandelic acid, was prepared using metal coordination-chelation interaction. By evaluating the recognition characteristics in the chromatographic mode, the recognition interactions were proposed: specific and nonspeci...

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Veröffentlicht in:中国化学快报(英文版) 2005-06, Vol.16 (6), p.797-800
Hauptverfasser: Ying LIU, Guo Sheng DING, Jun De WANG
Format: Artikel
Sprache:eng
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Zusammenfassung:O6; Molecularly imprinted polymer, exhibiting considerable enantioselectivity for L-mandelic acid, was prepared using metal coordination-chelation interaction. By evaluating the recognition characteristics in the chromatographic mode, the recognition interactions were proposed: specific and nonspecific metal coordination-chelation interaction and hydrophobic interaction were responsible for substrate binding on metal-complexing imprinted polymer; while the selective recognition only came from specific metal coordination-chelation interaction and specific hydrophobic interaction.
ISSN:1001-8417