Study on Bicoordination Chiral Inducement Catalysis of (R)-4-Thiazolidinecarboxylic Acid

Study on Bicoordination Chiral Inducement Catalysis of (R)-4-Thiazolidinecarboxylic Acid

The bicoordination chiral inducement catalysis of (R)-4-thiazolidinecarboxylic acid in the enantioselective borane reduction of prochiral ketones has been studied. The fact that the absolute configuration of the main product can be changed by simply using different operation methods was firstly veri...

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Veröffentlicht in:中国化学快报(英文版) 2004-12, Vol.15 (12), p.1419-1422
Hauptverfasser: Hui WANG, Wei Wei PEI, Guo Bin SUN, Wei Ping YE
Format: Artikel
Sprache:eng
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Zusammenfassung:The bicoordination chiral inducement catalysis of (R)-4-thiazolidinecarboxylic acid in the enantioselective borane reduction of prochiral ketones has been studied. The fact that the absolute configuration of the main product can be changed by simply using different operation methods was firstly verified. And the reason of bicoordination chiral inducement was discussed.
ISSN:1001-8417