Investigation on Luminescent Properties of Eu-doped GaN Polycrystalline Prepared by Solid-state Reaction
Eu-doped GaN was prepared by solid-state reaction with Ga2O3,Eu2O3 and NH3 applied as raw materials.The structural and optical properties were investigated.According to XRD results,wurtzite-type GaN powder without Eu2O3phase was obtained at 1000℃ and the grain size was about 20 run.Compared to the u...
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Veröffentlicht in: | 硅酸盐学报(英文版) 2016, Vol.3 (2), p.84-90 |
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Sprache: | eng |
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Zusammenfassung: | Eu-doped GaN was prepared by solid-state reaction with Ga2O3,Eu2O3 and NH3 applied as raw materials.The structural and optical properties were investigated.According to XRD results,wurtzite-type GaN powder without Eu2O3phase was obtained at 1000℃ and the grain size was about 20 run.Compared to the undoped GaN powder,all the Raman peaks of Eu-doped GaN powder were shifted towards lower phonon frequency about 2-6 cm-1,which may be resulted from the strain caused by the Eu3+ doping.The cathodo-luminescence(CL) spectra were measured from 80 to 293 K.Ultraviolet luminescence and Eu3+ luminescence were both observed when the temperature was below 200 K.When the temperature was increased to 293 K,the ultraviolet luminescence disappeared.However,the intensity of Eu3+ luminescence was nearly not influenced by temperature.A donor-acceptor pair(DAP) model based on ON and MgGa was pointed out for explaining the luminescence mechanism.The cathodo-luminescence spectra of nominal 1.0%,2.0%,3.0%and 5.0%(mole fraction) Eu-doped GaN at room temperature were summarized,which suggestes the 2.0%Eu-doped GaN has the highest Eu luminescent intensity. |
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ISSN: | 2095-7645 |
DOI: | 10.7521/j.issn.2095-7645.2016.02.05 |