Structure Analysis of Needle-like Copper Tantalum Trisulfide Crystals by XPS and Raman Spectroscopy

High-quality needle-like CuTaS3 single crystals have been synthesized through a chemical vapor transport(CVT) process.Crystallographic data show the special double chains of edge-sharing TaS6 octahedra.The detailed XPS analysis of CuTaS3 was undertaken and the valence states can be described by Cu+T...

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Veröffentlicht in:高等学校化学研究(英文版) 2012-03, Vol.28 (2), p.171-175
1. Verfasser: CHENG Dan, JIN Hua LI Ben-xian WANG Xiao-feng CHU Qing-xin LU Yang, LIU Xiao-yang ZHAO Xu-dong
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Sprache:eng
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Zusammenfassung:High-quality needle-like CuTaS3 single crystals have been synthesized through a chemical vapor transport(CVT) process.Crystallographic data show the special double chains of edge-sharing TaS6 octahedra.The detailed XPS analysis of CuTaS3 was undertaken and the valence states can be described by Cu+Ta5+3S2-.In addition,CuTaS3 crystals were characterized with Raman spectroscopy.
ISSN:1005-9040
2210-3171