Advances of ferrous and ferric M?ssbauer recoilless fractions in minerals and glasses

M?ssbauer spectroscopy has been used widely to characterize the ferric(Fe3+)and ferrous(Fe2+)propor-tions and coordination of solid materials.To obtain these accurately,the recoilless fraction is indispensi-ble.The recoilless fractions(f)of iron-bearing minerals,including oxides,oxyhydroxides,silicates,carbonates,phosphates and dichalcogenides,and silicate glasses were evaluated from the temperature dependence of their center shifts or absorption area with the Debye model approximation.Generally,the resolved Debye temperature(θD)of ferric iron in minerals,except dichalcogenides,through their cen-ter shifts ranging from 400 to 550 K,is significantly larger than ferrous iron ranging from 300 to 400 K,which is consistent with the conclusion from previous work.The resolved f(Fe3+)RT with the center shift model(CSM)ranges from 0.825 to 0.925,which is larger than that obtained for f(Fe2+)RT,which ranges from 0.675 to 0.750.Meanwhile,the θD and f resolved from temperature-dependence of absorption are generally lower than from center shifts,especially for ferric iron.The significant difference between f(Fe3+)and f(Fe2+)indicates the necessity of recoilless fraction correction on the Fe3+/(Fe3++Fe2+)resolved from M?ssbauer spectra.