对二甲苯和醋酸二元液体混合物在不同温度下的超额摩尔体积、粘度和热容

TQ0; Experimental densities, viscosities and heat capacities at different temperatures were presented overthe entire range of mole fraction for the binary mixture of p-xylene and acetic acid. Density values were used in thedetermination of excess molar volumes, VE. At the same time, the excess visco...

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Veröffentlicht in:中国化学工程学报(英文版) 2002, Vol.10 (5), p.604-609
Hauptverfasser: 杨长生, 马沛生, 唐多强, 尹秋响, 赵长伟
Format: Artikel
Sprache:chi
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Zusammenfassung:TQ0; Experimental densities, viscosities and heat capacities at different temperatures were presented overthe entire range of mole fraction for the binary mixture of p-xylene and acetic acid. Density values were used in thedetermination of excess molar volumes, VE. At the same time, the excess viscosity and excess molar heat capacitieswere calculated. The values of VE, ηE and cpE were fitted to the Redlich-Kister equation. Good agreements wereobserved. The excess molar volumes are positive with a large maximum value located in the central concentrationrange. The excess viscosity has an opposite trend to the excess molar volume VE. ηE values are negative over theentire range of the mixture. The cure of dependence of cEp on concentration has a special shape. The molecularinteraction between p-xylene and acetic acid is discussed.
ISSN:1004-9541