Organometallic Lewis Acids, Part LVIIII [1]. Directed Synthesis of Dinuclear Metal Carbonyl Complexes of Rhenium, Iron, Chromium, and Tungsten with a Single Unsupported Halide or Pseudohalide Bridge (Cl-, Br-, I-, CN-, C(CN)3 -, NCS-, PPh2 -, SH-) by Use of Re(CO)5FBF3

Organometallic Lewis Acids, Part LVIIII [1]. Directed Synthesis of Dinuclear Metal Carbonyl Complexes of Rhenium, Iron, Chromium, and Tungsten with a Single Unsupported Halide or Pseudohalide Bridge (Cl-, Br-, I-, CN-, C(CN)3 -, NCS-, PPh2 -, SH-) by Use of Re(CO)5FBF3

By use of Re(CO) FBF the complexes with a single unsupported halide or pseudohalide bridge [Cp(OC) Fe-X-Re(CO) BF (X=Cl, I, PPh ), (OC) M-X-Re(CO) (M=Cr, W; X=Br, I, CN, NCS, SH), (OC)5W-N≡C-C[-C≡N-Re(CO) BF , Cp(OC)(NC)Fe-C≡N-Re(CO) , and [(OC) Re-N -Re(CO) BF have been synthesized.

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Veröffentlicht in:Zeitschrift für Naturforschung. B, A journal of chemical sciences A journal of chemical sciences, 2014-12, Vol.69 (11), p.1215-1220
Hauptverfasser: Fritz, Peter M., Sacher, Wolfgang, Beck, Wolfgang
Format: Artikel
Sprache:eng
Schlagworte:
Carbonyl Metal Complexes
Chromium
Halide- and Pseudohalide-bridged Complexes
Iron
Pentacarbonylrheniumtetrafluoroborate
Rhenium
Tungsten
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Zusammenfassung:By use of Re(CO) FBF the complexes with a single unsupported halide or pseudohalide bridge [Cp(OC) Fe-X-Re(CO) BF (X=Cl, I, PPh ), (OC) M-X-Re(CO) (M=Cr, W; X=Br, I, CN, NCS, SH), (OC)5W-N≡C-C[-C≡N-Re(CO) BF , Cp(OC)(NC)Fe-C≡N-Re(CO) , and [(OC) Re-N -Re(CO) BF have been synthesized.
ISSN:0932-0776
1865-7117
DOI:10.5560/znb.2014-4095