Tetraammine Tetrafluorido Cerium(IV) Ammonia (1/1), [CeF4(NH3)4] · NH3

Tetraammine Tetrafluorido Cerium(IV) Ammonia (1/1), [CeF4(NH3)4] · NH3

The synthesis and crystal structure of the first ammine complex of a cerium fluoride, tetraammine tetrafluorido cerium(IV) ammonia (1/1), [CeF (NH ] ・NH , are presented. The compound crystallizes in the form of colorless, block-shaped single crystals in the tetragonal space group P4/ncc with a = 9.0...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Zeitschrift für Naturforschung. B, A journal of chemical sciences A journal of chemical sciences, 2011-08, Vol.66 (8), p.868-870
Hauptverfasser: Kraus, Florian, Baer, Sebastian A.
Format: Artikel
Sprache:eng
Schlagworte:
Ammine
Cerium
Crystal Structure
Fluoride
Liquid Ammonia
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
Beschreibung
Zusammenfassung:The synthesis and crystal structure of the first ammine complex of a cerium fluoride, tetraammine tetrafluorido cerium(IV) ammonia (1/1), [CeF (NH ] ・NH , are presented. The compound crystallizes in the form of colorless, block-shaped single crystals in the tetragonal space group P4/ncc with a = 9.03215(9), c = 10.96404(17) Å , V = 894.443(19) Å , and Z = 4. The compound contains discrete [CeF (NH ] molecules interconnected by N-H···F hydrogen bonds.
ISSN:0932-0776
1865-7117
DOI:10.1515/znb-2011-0815