Einkristallzüchtung und Röntgenstrukturanalyse der Fluoridcarbonate K3CO3F und Rb3CO3F / Crystal Growth and X-Ray Structure Determination of the Fluoride Carbonates K3CO3F and Rb3CO3F

The isostructural title compounds have been characterized by X-ray powder and single crystal diffraction: R 3̅ c; Z = 6; a = 741.81(4), c = 1639.18(9) pm; 389 diffractometer data, R = 0.04, R = 0.03 (K CO F); α = 776.1(3), c = 1741.2(9) pm; 235 diffractometer data, R = 0.07, R = 0.06 (Rb CO F). Both...

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Veröffentlicht in:Zeitschrift für Naturforschung. B, A journal of chemical sciences A journal of chemical sciences, 1990-07, Vol.45 (7), p.943-946
Hauptverfasser: Arlt, Joachim, Jansen, Martin
Format: Artikel
Sprache:eng
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Zusammenfassung:The isostructural title compounds have been characterized by X-ray powder and single crystal diffraction: R 3̅ c; Z = 6; a = 741.81(4), c = 1639.18(9) pm; 389 diffractometer data, R = 0.04, R = 0.03 (K CO F); α = 776.1(3), c = 1741.2(9) pm; 235 diffractometer data, R = 0.07, R = 0.06 (Rb CO F). Both compounds are carbonate fluorides with isolated CO and F anions.
ISSN:0932-0776
1865-7117
DOI:10.1515/znb-1990-0704