Alkyl-Functionalized Oxide-Free Silicon Nanoparticles: Synthesis and Optical Properties

Highly monodisperse silicon nanoparticles (1.57 ± 0.21 nm) are synthesized with a covalently attached alkyl monolayer on a gram scale. Infrared spectroscopy shows that these silicon nanoparticles contain only a few oxygen atoms per nanoparticle. XPS spectra clearly show the presence of unoxidized Si and attached alkyl chains. Owing to the relatively efficient synthesis (yields ≈100‐fold higher than of those previously reported) the molar extinction coefficient ε can be measured: εmax = 1.7 × 10−4 M−1cm−1, only a factor of 4 lower than that of CdS and CdSe nanoparticles of that size. The quantum yield of emission ranges from 0.12 (C10H21‐capping) to 0.23 (C16H33‐capping). UV/Vis absorption and emission spectroscopy show clear vibrational progressions (974 ± 14 cm−1; up to five vibrational bands visible at room temperature), resembling bulk SiC phonons, which support the monodispersity observed by TEM. This was also confirmed by time‐resolved fluorescence anisotropy measurements, which display a strictly monoexponential decay that can only be indicative of monodisperse, ball‐shaped nanoparticles. Highly monodisperse and unoxidized Si NPs (1.57 ± 0.21 nm) are synthesized with a covalently attached alkyl monolayer on a gram scale, confirmed by FTIR and XPS. UV/Vis absorption and emission spectroscopy display clear vibrational progressions (974 ± 14 cm−1; see image), which resembles bulk SiC phonons. Thissupports the monodispersity observed by TEM and time‐resolved fluorescence anisotropy measurements.