Concentration and temperature dependence of the structural, magnetic, and dielectric properties of La2Ni(Mn1-xRux)O6 solid solutions

The crystal structure, magnetic ordering, and dielectric characteristics of polycrystalline powder samples of La2NiMn1-xRuxO6 (x = 0.25-0.75) solid solutions have been studied. The X-ray diffraction results were analysed in detail, and reliably show that all compounds have a monoclinic (P2(1)/n) str...

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Hauptverfasser:	Pramanik, P, Ivanov, Sergey, Turkin, D. I, Bazuev, G. V, Joshi, D. C, Gyrdasova, O. I, Mathieu, Roland
Format:	Artikel
Sprache:	eng
Schlagworte:	Annan elektroteknik och elektronik Cationic order Condensed Matter Physics Den kondenserade materiens fysik Dielectric properties Insulating ferromagnets Magnetic oxides Other Electrical Engineering, Electronic Engineering, Information Engineering Structural properties
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Zusammenfassung:	The crystal structure, magnetic ordering, and dielectric characteristics of polycrystalline powder samples of La2NiMn1-xRuxO6 (x = 0.25-0.75) solid solutions have been studied. The X-ray diffraction results were analysed in detail, and reliably show that all compounds have a monoclinic (P2(1)/n) structure with Ni and Mn/Ru ions occupying the 2c and 2d sites, respectively. Magnetic susceptibility measurements reveal a ferromagnetic order for La2NiMn0.75Ru0.25O6 and La2NiMn0.5Ru0.5O6. The ferromagnetic transition temperature decreases from 200 K for La2NiMn0.75Ru0.25O6 to 175 K for La2NiMn0.5Ru0.5O6. Dielectric measurements show large dielectric constants (similar to 10(4)) at room temperature. In addition, the temperature-dependent loss-tangent Tan delta(T) curves reveal relaxation characteristics due to charge transfer between nearest cations.
DOI:	10.1016/j.jallcom.2023.171885