Settable compositions free of portland cement and associated methods of use

Methods of preparing improved settable compositions free of Portland cement and methods of using such compositions in subterranean operations are provided. An example of a method of preparing such compositions may comprise providing an unhydrated mixture of raw materials comprising a silica component, an aluminum component, a magnesium component, a sodium component, a calcium component, a ferrous or ferric component, a sulfurous component, and a potassium component, wherein the mixture has been formed without heating any of the components to above about 3000° F.; and adding water to the unhydrated mixture of raw materials to form a settable composition.