Use of metal complex compounds as oxidation catalysts

nmpzq 12345678910 11 11812 312 12 11813213 13 13 118131313 1313 13 131415 ⊕141516 1415 16 11814 15 12345678910 11 Use of metal complex compounds of formula [LMeX]Y  (1), wherein Me is manganese, titanium, iron, cobalt, nickel or copper, wherein R, R, R, R, R, R, R, R, R, Rand Rare each independently...

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Hauptverfasser: Schlingloff, Gunther, Wieprecht, Torsten, Bachmann, Frank, Dannacher, Josef, Dubs, Marie-Josée, Hazenkamp, Menno, Hänsler (-Richter), Grit, Schmidt, Brigitte, Schneider, Albert, Weingartner, Peter
Format: Patent
Sprache:eng
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Zusammenfassung:nmpzq 12345678910 11 11812 312 12 11813213 13 13 118131313 1313 13 131415 ⊕141516 1415 16 11814 15 12345678910 11 Use of metal complex compounds of formula [LMeX]Y  (1), wherein Me is manganese, titanium, iron, cobalt, nickel or copper, wherein R, R, R, R, R, R, R, R, R, Rand Rare each independently of the others hydrogen; unsubstituted or substituted C-Calkyl or aryl; cyano; halogen; nitro; -COORor -SORwherein Ris in each case hydrogen, a cation or unsubstituted or substituted C-Calkyl or aryl; -SR, -SORor -ORwherein Ris in each case hydrogen or unsubstituted or substituted C-Calkyl or aryl; -N(R)-NR′R″wherein R, R′and R″are as defined above for R; -NRRor -NRRRwherein R, Rand Rare each independently of the other(s) hydrogen or unsubstituted or substituted C-Calkyl or aryl, or Rand Rtogether with the nitrogen atom bonding them form an unsubstituted or substituted 5-, 6- or 7-membered ring which may optionally contain further hetero atoms; with the proviso that R, R, R, R, R, R, R, R, R, Rand Rare not simultaneously hydrogen, as catalysts for oxidation reactions, and the novel metal complex compounds of formula (1) and the novel ligands of formula (2).