Process for the production of unsymmetric and/or symmetric dialkyl carbonates and diols

A process for the production of a dialkyl carbonate and a diol, such as dimethyl carbonate and ethylene glycol, by reacting a feed containing a cyclic carbonate, a hydroxy alkyl carbonate and an aliphatic monohydric alcohol in the presence of a transesterification catalyst is described. In another a...

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Bibliographische Detailangaben
Hauptverfasser: Buchanan, J. Scott, Jiang, Zhaozhong, Santiesteban, Jose Guadalupe, Weber, William A
Format: Patent
Sprache:eng
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Zusammenfassung:A process for the production of a dialkyl carbonate and a diol, such as dimethyl carbonate and ethylene glycol, by reacting a feed containing a cyclic carbonate, a hydroxy alkyl carbonate and an aliphatic monohydric alcohol in the presence of a transesterification catalyst is described. In another aspect, a process is described which is particularly useful for producing unsymmetric dialkyl carbonates, such as ethyl methyl carbonate.