Metal-ligand complexes and related methods of chemical CO2 fixation
2 Salen complexes were found to be excellent catalysts for the reaction of terminal epoxides with COwhen used in conjunction with a Lewis base cocatalyst (DMAP). This catalyst system cleanly affords the product cyclic carbonates in high yield under mild reaction conditions and is applicable to a var...
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| Sprache: | eng |
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| Zusammenfassung: | 2 Salen complexes were found to be excellent catalysts for the reaction of terminal epoxides with COwhen used in conjunction with a Lewis base cocatalyst (DMAP). This catalyst system cleanly affords the product cyclic carbonates in high yield under mild reaction conditions and is applicable to a variety of terminal epoxides. |
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