Color photographic element containing a fragmentable electron donor for improved photographic response

This invention relates to a color photographic element having improved photographic response. This invention comprises a multicolor photographic element comprising a support bearing a cyan dye image-forming unit comprising at least one red-sensitive silver halide emulsion layer having associated the...

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Bibliographische Detailangaben
Hauptverfasser: Friday, James A, Pepe, Joseph P, Hansen, Jeffrey C, Muenter, Annabel A, Lenhard, Jerome R
Format: Patent
Sprache:eng
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Beschreibung
Zusammenfassung:This invention relates to a color photographic element having improved photographic response. This invention comprises a multicolor photographic element comprising a support bearing a cyan dye image-forming unit comprising at least one red-sensitive silver halide emulsion layer having associated therewith at least one cyan dye-forming coupler, a magenta dye image-forming unit comprising at least one green-sensitive silver halide emulsion layer having associated therewith at least one magenta dye-forming coupler, a yellow dye image-forming unit comprising at least one blue-sensitive silver halide emulsion layer having associated therewith at least one yellow dye-forming coupler, wherein at least one of said layers comprises large tabular grains having an average circular diameter of greater than 2 m and contains a fragmentable electron donating compound is of the formula: X-Y′ or a compound which contains a moiety of the formula -X-Y′; whereinX is an electron donor moiety, Y′ is a leaving proton H or a leaving group Y, with the proviso that if Y′ is a proton, a base, , is covalently linked directly or indirectly to X, and wherein:1) X-Y′ has an oxidation potential between 0 and about 1.4 V; and2) the oxidized form of X-Y′ undergoes a bond cleavage reaction to give the radical X. and the leaving fragment Y′; and, optionally,3) the radical X. has an oxidation potential −0.7V (that is, equal to or more negative than about −0.7V).