Fragmentable electron donor compounds combined with broad blue spectral sensitization

This invention relates to a photographic element and in particular a photographic element comprising at least one layer sensitized to blue light. This invention comprises a photographic element comprising a support and at least one blue sensitive silver halide emulsion layer containing a tabular gra...

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Bibliographische Detailangaben
Hauptverfasser: Reed, Kenneth J, Pepe, Joseph P, Friday, James A, Eikenberry, Jon N, Chang, Yun C, Muenter, Annabel A, Lenhard, Jerome R
Format: Patent
Sprache:eng
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Beschreibung
Zusammenfassung:This invention relates to a photographic element and in particular a photographic element comprising at least one layer sensitized to blue light. This invention comprises a photographic element comprising a support and at least one blue sensitive silver halide emulsion layer containing a tabular grain silver halide emulsion, or an emulsion in which the halide content is at least 50% chloride and no more than 5% iodide, wherein the emulsion is spectrally sensitized with at least one dye providing a peak sensitization between 446 and 500 nm and at least one dye providing a peak sensitization between 400 and 445 nm and additionally sensitized with a fragmentable electron donor of the formula: X-Y′. or an electron donor which contains an -XY′ moiety;whereinX is an electron donor moiety, Y′ is a leaving proton H or a leaving group Y, with the proviso that if Y′ is H a base, , is covalently linked directly or indirectly to X. and wherein:1) X-Y′ has an oxidation potential between 0 and about 1.4 V; and2) the oxidized form of X-Y′ fragments to give the radical X and the leaving fragment Y′; and, optionally,3) the radical X has an oxidation potential −0.7V (that is, equal to or more negative than about −0.7 V).