Ethylene copolymer compositions
The present invention relates to a novel ethylene copolymer and a method for producing the same. More particularly, the present invention is concerned with a novel ethylene copolymer comprising a copolymer of ethylene with at least one comonomer selected from the group comprising compounds represent...
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Zusammenfassung: | The present invention relates to a novel ethylene copolymer and a method for producing the same. More particularly, the present invention is concerned with a novel ethylene copolymer comprising a copolymer of ethylene with at least one comonomer selected from the group comprising compounds represented by the formula H
C CHR wherein R represents a C
-C
linear, branched or cyclic alkyl group or a C
-C
aryl group, and a C
-C
linear, branched or cyclic diene, and having a specific density, and having not only a specific molecular weight distribution characteristic but also a specific comonomer content distribution characteristic.
Disclosed is a novel ethylene copolymer by copolymerizing an ethylene and at least one comonomer selected from a compound represented by the formula HC CHR wherein R is an alkyl group or an aryl group, and a diene, by slurry polymerization process in the presence of a solid catalyst system comprising a support, a transition metal compound and an activator capable of converting the transition metal compound into a catalytically active transition metal complex. The produced copolymer has a density of from 0.870 to 0.980 and a molecular weight distribution (M/M) of from 3 to 10, and exhibiting GPC/FT-IR characteristics and CFC characteristics, both of which define a comonomer content distribution, wherein, in one aspect, the lower the molecular weight of a copolymer fraction in a molecular weight distribution of an ethylene copolymer, the lower the comonomer content of the copolymer fraction; and, in the other aspect, the higher the molecular weight of a copolymer fraction, the higher the comonomer content of the copolymer fraction, so that ethylene copolymer exhibits high impact strength and excellent ESCR properties. Further, the ethylene copolymer contains substantially no impurites such as a wax, a gel and the like. Thus, the ethylene copolymer and blend compositions therefrom can be advantageously used for the production of film, fibers, foams or sheets including blown film, cast films, laminate films, blow-molded articles, injection molded articles, pipes, coating materials for cables, and the like. |
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