Glycolysis process for recycling of post-consumer pet
The present invention is directed to a novel process for recycling post-consumer polyester. In particular, the process of the present invention involves depolymerization of the post-consumer polyester by way of glycolysis. Disclosed herein is a process for depolymerizing and purifying contaminated p...
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Zusammenfassung: | The present invention is directed to a novel process for recycling post-consumer polyester. In particular, the process of the present invention involves depolymerization of the post-consumer polyester by way of glycolysis.
Disclosed herein is a process for depolymerizing and purifying contaminated post-consumer polyester. In the process, depolymerization is effected by way of glycolysis in an agitated reactor vessel. The process includes the steps of contacting a contaminated polyester with an amount of a glycol to provide a molar ratio of greater than about 1 to about 5 total glycol units to total dicarboxylic acid units at a temperature between about 150 to about 300° C. and an absolute pressure of about 0.5 to about 3 bars. This reaction is conducted for a time sufficient to produce, in the reactor, an upper layer having a relatively low density contaminant floating on top of a lower layer which includes a relatively high density depolymerized oligomer of the polyester, and separating the upper layer from the lower layer. The layers may be separated by removing the upper layer from the reactor in a first stream and removing said lower layer from the reactor in a second stream. |
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