Metallic multilayer coating films formation process

The present invention relates to a novel process to form metallic multilayer coating films by using a non-leafing aluminum flake pigment. There is disclosed a process to form metallic multilayer coating films characterized by coating on the uncured coating surface of a paint formed on a substrate with a composition (B), which contains non-leafing aluminum flake and organic solvent and then by coating, optionally after coating with a topcoat paint (C), with a clear paint (D). According to said process metallic multilayer coating films, which is white, excellent in metallic luster impression and having a high flip-flop effect, can be formed by using non-leafing aluminum flake pigment.