Method for producing optionally substituted aliphatic, aromatic or heteroaromatic aldehydes
The invention relates to a method for producing optionally substituted aliphatic, aromatic or heteraromatic aldehydes of formula (I), whereby the R represents a C 1 -C 20 Alkyl radical, an aromatic or heteraromatic radical Ar which can optionally be substituted once or on a number of occasions by OH...
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creator | Heu, Ferdinand Hendel, Wolfram Poechlauer, Peter WInkler, Berthold |
description | The invention relates to a method for producing optionally substituted aliphatic, aromatic or heteraromatic aldehydes of formula (I), whereby the R represents a C
1
-C
20
Alkyl radical, an aromatic or heteraromatic radical Ar which can optionally be substituted once or on a number of occasions by OH, C
1
-C
6
alkyl, C
1
-C
6
alkoxy, C
1
-C
6
carboxylic acids or ester containing 1-6 C atoms in the ester part, phenyl, halogen, SO
3
H, NO
2
, NR
1
R
2
or SR
1
whereby R
1
and R
2
can be independently H, phenyl or C
1
-C
6
alkyl. The invention is characterised by a compound of formula (II) wherein R has the above meaning, a) is diazotized in an acidic medium, at a temperature of between −10 −+100 ° C. by a diazoation reagent and is transformed into the corresponding hydroxy carboxy acid whereby b) is transformed, by means of oxygen, into the appropriate aldehyde of formula (I) in the presence of a metal, the salt thereof, oxide or hydroxide as a catalyst. |
format | Patent |
fullrecord | <record><control><sourceid>uspatents_EFI</sourceid><recordid>TN_cdi_uspatents_applications_20030144558</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>20030144558</sourcerecordid><originalsourceid>FETCH-uspatents_applications_200301445583</originalsourceid><addsrcrecordid>eNqVjTELwjAQhbs4iPofbhUUqm3BXRQXNzeHciZXE4i5kLsM_fdaEHen9_h4H29e3a-kji0MnCFltsX4-ARO6jliCCNIeYh6LUoWMPjkUL3ZAGZ-TQ0-niOlzD-CwZIbLcmymg0YhFbfXFTr8-l2vGyLJFSKKj2mFLzB6U36fV039a5tu-7Q_LN9A1rpQ4Y</addsrcrecordid><sourcetype>Open Access Repository</sourcetype><iscdi>true</iscdi><recordtype>patent</recordtype></control><display><type>patent</type><title>Method for producing optionally substituted aliphatic, aromatic or heteroaromatic aldehydes</title><source>USPTO Published Applications</source><creator>Heu, Ferdinand ; Hendel, Wolfram ; Poechlauer, Peter ; WInkler, Berthold</creator><creatorcontrib>Heu, Ferdinand ; Hendel, Wolfram ; Poechlauer, Peter ; WInkler, Berthold</creatorcontrib><description>The invention relates to a method for producing optionally substituted aliphatic, aromatic or heteraromatic aldehydes of formula (I), whereby the R represents a C
1
-C
20
Alkyl radical, an aromatic or heteraromatic radical Ar which can optionally be substituted once or on a number of occasions by OH, C
1
-C
6
alkyl, C
1
-C
6
alkoxy, C
1
-C
6
carboxylic acids or ester containing 1-6 C atoms in the ester part, phenyl, halogen, SO
3
H, NO
2
, NR
1
R
2
or SR
1
whereby R
1
and R
2
can be independently H, phenyl or C
1
-C
6
alkyl. The invention is characterised by a compound of formula (II) wherein R has the above meaning, a) is diazotized in an acidic medium, at a temperature of between −10 −+100 ° C. by a diazoation reagent and is transformed into the corresponding hydroxy carboxy acid whereby b) is transformed, by means of oxygen, into the appropriate aldehyde of formula (I) in the presence of a metal, the salt thereof, oxide or hydroxide as a catalyst.</description><language>eng</language><creationdate>2003</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20030144558$$EPDF$$P50$$Guspatents$$Hfree_for_read</linktopdf><link.rule.ids>230,308,776,869,881,64032</link.rule.ids><linktorsrc>$$Uhttps://patentcenter.uspto.gov/applications/10311272$$EView_record_in_USPTO$$FView_record_in_$$GUSPTO$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>Heu, Ferdinand</creatorcontrib><creatorcontrib>Hendel, Wolfram</creatorcontrib><creatorcontrib>Poechlauer, Peter</creatorcontrib><creatorcontrib>WInkler, Berthold</creatorcontrib><title>Method for producing optionally substituted aliphatic, aromatic or heteroaromatic aldehydes</title><description>The invention relates to a method for producing optionally substituted aliphatic, aromatic or heteraromatic aldehydes of formula (I), whereby the R represents a C
1
-C
20
Alkyl radical, an aromatic or heteraromatic radical Ar which can optionally be substituted once or on a number of occasions by OH, C
1
-C
6
alkyl, C
1
-C
6
alkoxy, C
1
-C
6
carboxylic acids or ester containing 1-6 C atoms in the ester part, phenyl, halogen, SO
3
H, NO
2
, NR
1
R
2
or SR
1
whereby R
1
and R
2
can be independently H, phenyl or C
1
-C
6
alkyl. The invention is characterised by a compound of formula (II) wherein R has the above meaning, a) is diazotized in an acidic medium, at a temperature of between −10 −+100 ° C. by a diazoation reagent and is transformed into the corresponding hydroxy carboxy acid whereby b) is transformed, by means of oxygen, into the appropriate aldehyde of formula (I) in the presence of a metal, the salt thereof, oxide or hydroxide as a catalyst.</description><fulltext>true</fulltext><rsrctype>patent</rsrctype><creationdate>2003</creationdate><recordtype>patent</recordtype><sourceid>EFI</sourceid><recordid>eNqVjTELwjAQhbs4iPofbhUUqm3BXRQXNzeHciZXE4i5kLsM_fdaEHen9_h4H29e3a-kji0MnCFltsX4-ARO6jliCCNIeYh6LUoWMPjkUL3ZAGZ-TQ0-niOlzD-CwZIbLcmymg0YhFbfXFTr8-l2vGyLJFSKKj2mFLzB6U36fV039a5tu-7Q_LN9A1rpQ4Y</recordid><startdate>20030731</startdate><enddate>20030731</enddate><creator>Heu, Ferdinand</creator><creator>Hendel, Wolfram</creator><creator>Poechlauer, Peter</creator><creator>WInkler, Berthold</creator><scope>EFI</scope></search><sort><creationdate>20030731</creationdate><title>Method for producing optionally substituted aliphatic, aromatic or heteroaromatic aldehydes</title><author>Heu, Ferdinand ; Hendel, Wolfram ; Poechlauer, Peter ; WInkler, Berthold</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-uspatents_applications_200301445583</frbrgroupid><rsrctype>patents</rsrctype><prefilter>patents</prefilter><language>eng</language><creationdate>2003</creationdate><toplevel>online_resources</toplevel><creatorcontrib>Heu, Ferdinand</creatorcontrib><creatorcontrib>Hendel, Wolfram</creatorcontrib><creatorcontrib>Poechlauer, Peter</creatorcontrib><creatorcontrib>WInkler, Berthold</creatorcontrib><collection>USPTO Published Applications</collection></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext_linktorsrc</fulltext></delivery><addata><au>Heu, Ferdinand</au><au>Hendel, Wolfram</au><au>Poechlauer, Peter</au><au>WInkler, Berthold</au><format>patent</format><genre>patent</genre><ristype>GEN</ristype><title>Method for producing optionally substituted aliphatic, aromatic or heteroaromatic aldehydes</title><date>2003-07-31</date><risdate>2003</risdate><abstract>The invention relates to a method for producing optionally substituted aliphatic, aromatic or heteraromatic aldehydes of formula (I), whereby the R represents a C
1
-C
20
Alkyl radical, an aromatic or heteraromatic radical Ar which can optionally be substituted once or on a number of occasions by OH, C
1
-C
6
alkyl, C
1
-C
6
alkoxy, C
1
-C
6
carboxylic acids or ester containing 1-6 C atoms in the ester part, phenyl, halogen, SO
3
H, NO
2
, NR
1
R
2
or SR
1
whereby R
1
and R
2
can be independently H, phenyl or C
1
-C
6
alkyl. The invention is characterised by a compound of formula (II) wherein R has the above meaning, a) is diazotized in an acidic medium, at a temperature of between −10 −+100 ° C. by a diazoation reagent and is transformed into the corresponding hydroxy carboxy acid whereby b) is transformed, by means of oxygen, into the appropriate aldehyde of formula (I) in the presence of a metal, the salt thereof, oxide or hydroxide as a catalyst.</abstract><oa>free_for_read</oa></addata></record> |
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recordid | cdi_uspatents_applications_20030144558 |
source | USPTO Published Applications |
title | Method for producing optionally substituted aliphatic, aromatic or heteroaromatic aldehydes |
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