Method for producing optionally substituted aliphatic, aromatic or heteroaromatic aldehydes

The invention relates to a method for producing optionally substituted aliphatic, aromatic or heteraromatic aldehydes of formula (I), whereby the R represents a C 1 -C 20 Alkyl radical, an aromatic or heteraromatic radical Ar which can optionally be substituted once or on a number of occasions by OH...

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Hauptverfasser: Heu, Ferdinand, Hendel, Wolfram, Poechlauer, Peter, WInkler, Berthold
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creator Heu, Ferdinand
Hendel, Wolfram
Poechlauer, Peter
WInkler, Berthold
description The invention relates to a method for producing optionally substituted aliphatic, aromatic or heteraromatic aldehydes of formula (I), whereby the R represents a C 1 -C 20 Alkyl radical, an aromatic or heteraromatic radical Ar which can optionally be substituted once or on a number of occasions by OH, C 1 -C 6 alkyl, C 1 -C 6 alkoxy, C 1 -C 6 carboxylic acids or ester containing 1-6 C atoms in the ester part, phenyl, halogen, SO 3 H, NO 2 , NR 1 R 2 or SR 1 whereby R 1 and R 2 can be independently H, phenyl or C 1 -C 6 alkyl. The invention is characterised by a compound of formula (II) wherein R has the above meaning, a) is diazotized in an acidic medium, at a temperature of between −10 −+100 ° C. by a diazoation reagent and is transformed into the corresponding hydroxy carboxy acid whereby b) is transformed, by means of oxygen, into the appropriate aldehyde of formula (I) in the presence of a metal, the salt thereof, oxide or hydroxide as a catalyst.
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The invention is characterised by a compound of formula (II) wherein R has the above meaning, a) is diazotized in an acidic medium, at a temperature of between −10 −+100 ° C. by a diazoation reagent and is transformed into the corresponding hydroxy carboxy acid whereby b) is transformed, by means of oxygen, into the appropriate aldehyde of formula (I) in the presence of a metal, the salt thereof, oxide or hydroxide as a catalyst.</description><language>eng</language><creationdate>2003</creationdate><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://image-ppubs.uspto.gov/dirsearch-public/print/downloadPdf/20030144558$$EPDF$$P50$$Guspatents$$Hfree_for_read</linktopdf><link.rule.ids>230,308,776,869,881,64032</link.rule.ids><linktorsrc>$$Uhttps://patentcenter.uspto.gov/applications/10311272$$EView_record_in_USPTO$$FView_record_in_$$GUSPTO$$Hfree_for_read</linktorsrc></links><search><creatorcontrib>Heu, Ferdinand</creatorcontrib><creatorcontrib>Hendel, Wolfram</creatorcontrib><creatorcontrib>Poechlauer, Peter</creatorcontrib><creatorcontrib>WInkler, Berthold</creatorcontrib><title>Method for producing optionally substituted aliphatic, aromatic or heteroaromatic aldehydes</title><description>The invention relates to a method for producing optionally substituted aliphatic, aromatic or heteraromatic aldehydes of formula (I), whereby the R represents a C 1 -C 20 Alkyl radical, an aromatic or heteraromatic radical Ar which can optionally be substituted once or on a number of occasions by OH, C 1 -C 6 alkyl, C 1 -C 6 alkoxy, C 1 -C 6 carboxylic acids or ester containing 1-6 C atoms in the ester part, phenyl, halogen, SO 3 H, NO 2 , NR 1 R 2 or SR 1 whereby R 1 and R 2 can be independently H, phenyl or C 1 -C 6 alkyl. 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title Method for producing optionally substituted aliphatic, aromatic or heteroaromatic aldehydes
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