Method for producing optionally substituted aliphatic, aromatic or heteroaromatic aldehydes
The invention relates to a method for producing optionally substituted aliphatic, aromatic or heteraromatic aldehydes of formula (I), whereby the R represents a C 1 -C 20 Alkyl radical, an aromatic or heteraromatic radical Ar which can optionally be substituted once or on a number of occasions by OH...
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Format: | Patent |
Sprache: | eng |
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Zusammenfassung: | The invention relates to a method for producing optionally substituted aliphatic, aromatic or heteraromatic aldehydes of formula (I), whereby the R represents a C
1
-C
20
Alkyl radical, an aromatic or heteraromatic radical Ar which can optionally be substituted once or on a number of occasions by OH, C
1
-C
6
alkyl, C
1
-C
6
alkoxy, C
1
-C
6
carboxylic acids or ester containing 1-6 C atoms in the ester part, phenyl, halogen, SO
3
H, NO
2
, NR
1
R
2
or SR
1
whereby R
1
and R
2
can be independently H, phenyl or C
1
-C
6
alkyl. The invention is characterised by a compound of formula (II) wherein R has the above meaning, a) is diazotized in an acidic medium, at a temperature of between −10 −+100 ° C. by a diazoation reagent and is transformed into the corresponding hydroxy carboxy acid whereby b) is transformed, by means of oxygen, into the appropriate aldehyde of formula (I) in the presence of a metal, the salt thereof, oxide or hydroxide as a catalyst. |
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