Photographic element with improved sensitivity and improved keeping
This invention comprises a photographic element comprising at least one light-sensitive silver halide emulsion layer containing a fragmentable electron donating compound of the formula: X-Y′ or a compound which contains a moiety of the formula -X-Y′; wherein X is an electron donor moiety, Y′ is a le...
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Zusammenfassung: | This invention comprises a photographic element comprising at least one light-sensitive silver halide emulsion layer containing a fragmentable electron donating compound of the formula: X-Y′ or a compound which contains a moiety of the formula -X-Y′; wherein
X is an electron donor moiety, Y′ is a leaving proton H or a leaving group Y, with the proviso that if Y′ is a proton, a base,
−
, is present in the emulsion layer, and wherein:
1) X-Y′ has an oxidation potential between 0 and about 1.4 V; and
2) the oxidized form of X-Y′ undergoes a bond cleavage reaction to give the radical X. and the leaving fragment Y′; and
3) the radical X. has an oxidation potential >−0.7V; said photographic element further comprising a reductone of the Formula 2:
1
wherein R
23
and R
24
are the same or different, and may represent H, alkyl, cycloalkyl, aryl, or an alkyl group with a solubilizing group such as -OH, sulfonamide, sulfamoyl, or carbamoyl, or R
23
and R
24
may be joined to complete a heterocyclic ring, R
21
and R
22
are H, OH, alkyl, aryl, cycloalkyl, or may together represent an alkylidene group, n is 1 or 2 and R
20
is H, alkyl, aryl, or CO
2
R
25
where R
25
is alkyl. In a preferred embodiment of the invention, the photographic element is a multicolor photographic element. |
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