SELF-HEALING COPOLYMERIZED POLYCARBONATE AND PREPARATION METHOD THEREFOR
The invention relates to a self-healing copolymerized polycarbonate and a preparation method thereof. The method comprises the following steps: mixing a reducing sugar, an oxetane derivative and a first catalyst, heating and reacting at 50 to 80° C. for 0.5 to 2 h to obtain the first product; adding...
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Sprache: | eng |
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Zusammenfassung: | The invention relates to a self-healing copolymerized polycarbonate and a preparation method thereof. The method comprises the following steps: mixing a reducing sugar, an oxetane derivative and a first catalyst, heating and reacting at 50 to 80° C. for 0.5 to 2 h to obtain the first product; adding a diol, a diester and a second catalyst to the first product, and then heating to 180 to 220° C. for 2 to 4 h to obtain an oligomer; heating the oligomer to 230 to 270° C. and holding at the temperature and reacting for 1 to 3 h to obtain a self-healing copolymerized polycarbonate. The self-healing copolymerized polycarbonate material prepared by the method of the invention has self-healing property and biodegradability, which ensures the consistency and uniformity of the product. In addition, the block introduced into the main chain is green and environmentally friendly, and the original intention of clean production of polycarbonate has not been changed. |
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