Propylene epoxidation with in situ generated H2O2 in supercritical conditions

[EN] Several bi-functional materials based on palladium nanoparticles supported onto nanocrystalline tita-nium silicalite zeolite (Pd@TS-1) were prepared and used as active and reusable catalysts to direct POproduction from hydrogen, oxygen and propylene through one-pot two-step combined process. Thistype of catalysts was able to carry out the consecutive process where palladium nanoparticles catalyzed the formation of H2O2that was used as intermediate reagent for propylene epoxidation catalyzed byTS-1 nanocrystals, used as supporting active matrix. Influence of supercritical CO2conditions in batch reactions was evaluated together with the associated effect due to the presence of platinum promoters (Pd(Pt)@TS-1). Other reaction parameters were also considered, such as palladium loading, use of acid-ity inhibitors and modification of H2/O2/C3ratio. Reusability studies showed the high stability of thec atalysts in consecutive catalytic cycles, their regeneration being possible. The research leading to these results has received funding from European Community's Seventh Framework Program, through the Collaborative Project INCAS, Contract Nr. NMP2-LA-2010-245988. AP and UD thank additional funds from Spanish Government (MAT2011-29020-C02-01, Consolider-Ingenio MULTICAT C5D2009-00050 Prieto Arnal, A.; Palomino Roca, M.; Díaz Morales, UM.; Corma Canós, A. (2014). Propylene epoxidation with in situ generated H2O2 in supercritical conditions. Catalysis Today. 227:87-95. https://doi.org/10.1016/j.cattod.2013.10.004