A Ferromagnetic Salicylaldoximate/Azide MnII2MnIII6 Cluster with an S = 17 Ground State and a Single-Molecule-Magnet Response

One new MnII 2MnIII 6 cluster exhibiting an S = 17 spin ground state and single-molecule-magnet properties has been designed linking MnIII 3-salicylaldoximate triangles and tetracoordinated MnII cations by means of end-on azido bridges. The ferromagnetic coupling has been rationalized as a function...

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Hauptverfasser:	Vicente Castillo, Ramón, El Fallah El Boufrahi, Mohamed Salah, Casanovas Bayo, Berta, Font Bardia, Ma. Mercedes, Escuer Fité, Albert
Format:	Artikel
Sprache:	eng
Schlagworte:	Estructura cristal·lina (Sòlids) Geochemistry Geoquímica Layer structure (Solids) Magnetism Magnetisme
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Beschreibung
Zusammenfassung:	One new MnII 2MnIII 6 cluster exhibiting an S = 17 spin ground state and single-molecule-magnet properties has been designed linking MnIII 3-salicylaldoximate triangles and tetracoordinated MnII cations by means of end-on azido bridges. The ferromagnetic coupling has been rationalized as a function of their structural parameters.
ISSN:	0020-1669
DOI:	10.1021/acs.inorgchem.6b00662