Synthesis, spectral characterization and biological applications of tri-and diorganotin (IV) derivatives of 2-[N-(2,6-dichloro-3-methylphenyl) amino] benzoic acid
A series of tri- and diorganotin(IV) compounds with the general formulae $R_3SnL$ and $R_2SnL_2$ (where R = Me, n-Bu, Ph and L = 2-[N-(2,6-dichloro-3-methylphenyl)-amino]benzoate) were synthesized. These compounds were characterized by different instrumental methods such as infrared, multinuclear NM...
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Veröffentlicht in: | Turkish journal of chemistry 2004, Vol.28 (1), p.17-26 |
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Hauptverfasser: | , , , , , , |
Format: | Artikel |
Sprache: | eng |
Online-Zugang: | Volltext |
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Zusammenfassung: | A series of tri- and diorganotin(IV) compounds with the general formulae $R_3SnL$ and $R_2SnL_2$ (where R = Me, n-Bu, Ph and L = 2-[N-(2,6-dichloro-3-methylphenyl)-amino]benzoate) were synthesized. These compounds were characterized by different instrumental methods such as infrared, multinuclear NMR ($^1H$, $^{13}C$, $^{119}Sn$) and mass spectrometry. The spectroscopic investigation illustrates that the carboxylate group acts as a bidentate in solid state and as a monodentate in solution. Biological screening tests reveal that the investigated compounds have potential as antibacterial agents. |
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ISSN: | 1300-0527 1303-6130 |